Mike,
No, you can't have more than one primary key in a table.
It is not clear what, or more importantly why, you are asking. If you
mean you want more than one field where duplicate values are not
permitted, then set the Indexed property of such a field to 'Yes (No
Duplicates)'... this does not make this field a primary key though.
If you mean you want the primary key to be comprised of a combination
of more than one field, you can do this too... Hold down the Ctrl key
and select both fields in table design with the mouse, and then click
the primary key toolbar icon.
- Steve Schapel, Microsoft Access MVP