You can't change the column labels. You hide them using Tools>Options>View
and uncheck "row and column headers".
In row 1 enter some meaningful labels(titles) for the columns.
Select A2 and Window>Freeze Panes to lock row 1 in view as you scroll down the
sheet.
If you select B2 and Freeze Panes, row 1 and column A will be locked in view.
Gord Dibben Excel MVP
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