Hamricka, you're saying these values are actually strings (eg "<0.1") rather
than numeric values (eg 0.1)? If so, I think you need a helper column, each
cell of which strips off the '<' and calculates the value; you can take the
MAX of that column.
Say your string values are in col A; in row 2 of your helper column the
formula would be =VALUE(MID(A2,2,9)). The MID takes the string starting with
the second position out to the end, and the VALUE converts it from a string
to a number. After that you can use MAX against that column.
If you're getting this sheet from someone else that's about the best you can
do. But if you're preparing this sheet for someone else, who for some reason
needs to see the '<', you can do without the translation and just have the
cell format display the '<' without it affecting the actual value stored in
the cell. By that method, the value in your second row would be 0.1 (not
"<0.1"), and to get Excel to display it with a '<' just set the format to
include the '<' as part of the output. Do you know how to do that?