Hi Noah:
Hmmm... The Help on this topic is utterly useless, isn't it?
OK, so allow me to re-purpose something I wrote last year:
The TOC, Table of Figures, List of Tables etc are all created with the Table
of Contents Generator, an automatic Word tool that fills a TOC field.
We could call them all "TOC"s even though the kind you want is a Table of
Figures.
A TOC is "collected" from entries in your text. The process is described in
the Help topic "About creating a table of figures"
The Table of Figures consists of GENERATED text. Only the characters are
copied from the body of the document: the formatting is left behind. Study
the Help topic "Field codes: TOC (Table of Contents) field". In your case,
you are interested only in the \w and \x switches. These control whether or
not tabs and new line characters are copied in to the Table of Figures along
with the text.
Formatting of a TOC/TOF etc is performed automatically by Word. You need to
adjust how it does this.
The first thing you need to adjust is the "Format kind" that you choose when
you insert the List of Figures. Under Insert>Index and Tables>Table of
Figures you will see Formats box on the left.
CHOOSE "FROM TEMPLATE". If you choose any other Format, you have no control
over the formatting of your Table of Figures at all.
The Table of Figures is formatted by the built-in Paragraph style "Table of
Figures". This style will not exist in the document until after you have
inserted a Table of Figures.
Once the style exists, you can use Format>Style... To set the properties to
any font, size, and justification you choose.
If you choose any of the other Formats, the format of that style is
overwritten by Word every time the Table of Figures is generated or updated.
That's why you must choose the Format "From Template" when you start.
You can adjust the format of the Table of Figures style by clicking the
Modify button on the Insert>Index and Tables>Table of Figures dialog.
However, I usually don't: I prefer the better control I get with
Format>Style...
Once you have adjusted that style to your taste, check the Add to Template
box on the Modify Style dialog so you write the style into your template for
use next time.
No, you cannot define ANY of your own TOC style names. The TOC generator
can use only the built-in style names. But you can (and should) format
those styles to suit yourself.