It's like Jezebel says, ithe layout is mainly down to accurate positioning.
Try typing "Word CD label template" into Google and if should avoid you
having to do all the intial spacial design. If you really want to do it
yurself come back. From there on in try adding text boxes with "No fill" &
"No line" specified. Don't forget you can use "Order" to overlay stuff in the
way you want.
Hope this helps