The toolbars that are displayed by Word are stored in the document templates
and the documents themselves. By default they are stored in the normal
template. If you open a blank document and make changes to the toolbar
display, when you close Word you should be prompted (if the option is set in
tools > options> save) to save the normal template. Save it! The principles
involved are very similar to those at
http://word.mvps.org/FAQs/AppErrors/BlankDocNotBlank.htm
May I suggest that you create custom toolbars to carry your additional
buttons.
As PJY indicates you can move custom toolbars between open
documents/templates using the Organizer. If the required template is not
open in one of the Organizer windows, close the File and open the required
one.
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Graham Mayor - Word MVP
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