In short your files will be bigger with PNG than JPG.
Neither format will affect usability/compatibility.
I'm not so sure with this compatibility problems.
Our PPT mac users heavily use the screen copy procedure included in
the mac system (the famous apple-ctrl-4). This used to copy a JPEG
image in the clipboard on previous versions of Mac OS X. Since a
couple of month (one year?), Apple shifted to PNG as the default
format.
As a result, a number of PPT presentations made on mac could not
display images correctly on PCs. It seems the version of Powerpoint PC
might be important.
So I would not say that the change to PNG will not affect
compatibility.
After some problems, we decided to revert the screen copy image format
to JPEG (using the excellent and free ToolsX utility).
But I agree that for printing purposes, the PNG format is better.
Sorry for my approximate English technical terms, as my software is in
French.
Cheers,